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Item Details
Title: METAL-METAL BONDS AND CLUSTERS IN CHEMISTRY AND CATALYSIS
By: John P. Fackler Jr. (Editor)
Format: Hardback

List price: £139.99


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ISBN 10: 0306435276
ISBN 13: 9780306435270
Publisher: SPRINGER SCIENCE+BUSINESS MEDIA
Pub. date: 30 September, 1990
Edition: 1990 ed.
Series: Industry-University Cooperative Chemistry Program Symposia
Pages: 342
Description: Proceedings of the Seventh Industry-University Cooperative Chemistry Program held at Texas A&M University, College Station, Texas, March 20-23, 1989.
Synopsis: This book contains a series of papers and abstracts from the 7th Industry-University Cooperative Chemistry Program symposium held in the spring of 1989 at Texas A&M University. The symposium was larger than previous IUCCP symposia since it also celebrated the 25 years that had elapsed since the initial discovery by F. A. Cotton and his co-workers of the existence of metal-metal quadruple bonds. Cotton's discovery demonstrated that multiple bonding in inorganic systems is not governed by the same constraints observed in organic chemistry regarding s and p orbital involvement. The d orbitals are involved in the multiple bonding description. The quadruple bond involves considerable d orbital overlap between adjacent metal centers. Part I of this series of papers focuses upon the impact of this discovery and describes further contributions to the development of the field. Multiple metal-metal bonding now is known to permeate broad areas of transition metal chemistry. The understanding of metal-metal bonding that developed as a result of the discovery of multiple metal-metal bonding awakened a new chemistry involving metal clusters. Clusters were defined by Cotton to be species containing metal-metal bonding. Clusters in catalysis therefore seemed a logical grouping of papers in this symposium. Clusters play an every increasing role in the control of chemical reactions. Part II of this book describes some of the interesting new developments in this field. In Part III the papers examine the role clusters play in describing and understanding solid state materials.
Illustrations: X, 342 p.
Publication: US
Imprint: Kluwer Academic/Plenum Publishers
Returns: Returnable
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