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Item Details
Title: MAGNETIC FUNCTIONS BEYOND THE SPIN-HAMILTONIAN
By: R. Boca, D. M. P. Mingos (Editor)
Format: Hardback

List price: £279.99


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ISBN 10: 354026079X
ISBN 13: 9783540260790
Publisher: SPRINGER-VERLAG BERLIN AND HEIDELBERG GMBH & CO. KG
Series: Structure and Bonding v.117
Pages: 278
Description: Using the spin-Hamiltonian formalism, this work introduces the magnetic parameters through the components of the Lambda-tensor involving only the matrix elements of the angular momentum operator. It presents theoretical formulae necessary in performing the energy level calculations for a multi-term system.
Synopsis: Using the spin-Hamiltonian formalism the magnetic parameters are introduced through the components of the Lambda-tensor involving only the matrix elements of the angular momentum operator. The energy levels for a variety of spins are generated and the modeling of the magnetization, the magnetic susceptibility and the heat capacity is done. Theoretical formulae necessary in performing the energy level calculations for a multi-term system are prepared with the help of the irreducible tensor operator approach. The goal of the programming lies in the fact that the entire relevant matrix elements (electron repulsion, crystal field, spin-orbit interaction, orbital-Zeeman, and spin-Zeeman operators) are evaluated in the basis set of free-atom terms. The modeling of the zero-field splitting is done at three levels of sophistication. The spin-Hamiltonian formalism offers simple formulae for the magnetic parameters by evaluating the matrix elements of the angular momentum operator in the basis set of the crystal-field terms. The magnetic functions for dn complexes are modeled for a wide range of the crystal-field strengths.
Illustrations: 77 black & white tables, biography
Publication: Germany
Imprint: Springer-Verlag Berlin and Heidelberg GmbH & Co. K
Returns: Returnable
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BONDING AND CHARGE DISTRIBUTION IN POLYOXOMETALATES: A BOND VALENCE APPROACH (PB)
CHEMICAL HARDNESS (HB)
ESSENTIAL TRENDS IN INORGANIC CHEMISTRY (PB)
ESSENTIALS OF INORGANIC CHEMISTRY 1 (PB)
ESSENTIALS OF INORGANIC CHEMISTRY 2 (PB)
FUEL CELLS AND HYDROGEN STORAGE (HB)
FUEL CELLS AND HYDROGEN STORAGE (PB)
HIGH PERFORMANCE NON-OXIDE CERAMICS (HB)
LIQUID CRYSTALS (PB)
LIQUID CRYSTALS I (HB)
LIQUID CRYSTALS I (PB)
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MAGNETIC FUNCTIONS BEYOND THE SPIN-HAMILTONIAN (PB)
MOLECULAR ELECTRONIC STRUCTURES OF TRANSITION METAL COMPLEXES I (PB)
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MOLECULAR ELECTRONIC STRUCTURES OF TRANSITION METAL COMPLEXES II (PB)
ORGANOMETALLIC COMPOUNDS OF NICKEL, PALLADIUM, PLATINUM, COPPER, SILVER AND GOLD (PB)
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SEMICONDUCTOR NANOCRYSTALS AND SILICATE NANOPARTICLES (HB)
SEMICONDUCTOR NANOCRYSTALS AND SILICATE NANOPARTICLES (PB)
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STRUCTURAL AND ELECTRONIC PARADIGMS IN CLUSTER CHEMISTRY (PB)
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