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Item Details
| Title:
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THE CHEMISTRY OF ROTATIONAL ISOMERS
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| By: |
Michinori Oki |
| Format: |
Hardback |
| List price:
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£72.00 |
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We currently do not stock this item, please contact the publisher directly for
further information.
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| ISBN 10: |
3540561935 |
| ISBN 13: |
9783540561934 |
| Publisher: |
SPRINGER-VERLAG BERLIN AND HEIDELBERG GMBH & CO. KG |
| Pub. date: |
25 June, 1993 |
| Series: |
Reactivity and Structure: Concepts in Organic Chemistry 30 |
| Pages: |
172 |
| Description: |
Organic chemical compounds exhibiting atropisomerism are important substances for investigating intermolecular interactions. This monograph, designed for physical and synthetic organic chemists, investigates two classes of compounds that have stable rotational isomers at room temperature. |
| Synopsis: |
Rotation about the Carbon-Carbon single bond is generallyregarded to be unrestricted. About 50 years ago, rotationalisomers were found to exhibit optical activity: substitutedbiphenyl derivatives. However, the author has investigatedother classes of compounds that have stable rotationalisomers at room temperature. These compounds can serve asmodels for studying very weak intermolecular interactions,that are difficult to observe. Even diastereotopic groupsshow different chemical reactivity.From the contents: The "Free Rotation Concept" - RotamerPopulations - Barriers to Rotation - Reactivity ofRotational Isomers. |
| Illustrations: |
42 Tables, black and white; 1 Illustrations, black and white; X, 172 p. 1 |
| Publication: |
Germany |
| Imprint: |
Springer-Verlag Berlin and Heidelberg GmbH & Co. K |
| Returns: |
Non-returnable |
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