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Item Details
Title:
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RADICAL CHEMISTRY: THE FUNDAMENTALS
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By: |
John Perkins |
Format: |
Paperback |
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List price:
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£29.99 |
Our price: |
£26.24 |
Discount: |
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You save:
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£3.75 |
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ISBN 10: |
0198792891 |
ISBN 13: |
9780198792895 |
Availability: |
Usually dispatched within 1-3 weeks.
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Stock: |
Currently 0 available |
Publisher: |
OXFORD UNIVERSITY PRESS |
Pub. date: |
11 May, 2000 |
Series: |
Oxford Chemistry Primers 91 |
Pages: |
92 |
Description: |
The 'radicals' which are the principal subject of this book are reactive molecular fragments which may participate in chemical reactions. It has come to be recognised that these species, which may be quite indiscriminate in their mode of action, are important mediators of change within living organisms. This may be beneficial, though it is frequently associated with disease. At the same time, chemists have learnt how radical reactivity may often be tamed and put touse in the synthesis of complex molecules. This book sets out to provide a reader who has a grounding in organic chemistry with a basic understanding of radical behaviour upon which these important developments in chemistry and biology are being constructed. |
Synopsis: |
It is exactly 100 years since Moses Gomberg claimed that he had observed a substance containing a trivalent carbon atom i.e. a carbon-centred 'free radical' (nowadays, simply a carbon-centred 'radical'). The subsequent development of radical chemistry was at first very slow, but blossomed with the development of synthetic polymers, especially during and after World War II. In what is now generally understood by radical chemistry we are dealing with reactive, short-lived species which are electrically neutral. By the late 1960s, the essential features of the subject were well understood, and quantitative data on the energetics and kinetics of reactive radicals were rapidly accumalating.This short text sets out to present that basic understanding in a modern context, in which extensive use of radical reactions is now being made in organic synthesis, and where, in the life sciences, reactive radicals are being recognised both as mediators of many disease conditions, and frequently as key players in mechanisms of enzyme action. |
Illustrations: |
numerous line illustrations |
Publication: |
UK |
Imprint: |
Oxford University Press |
Returns: |
Returnable |
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