HANDBOOK OF REAGENTS FOR ORGANIC SYNTHESIS by Philip L. Fuchs (Editor) ( 9780470710234 )

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Title:

HANDBOOK OF REAGENTS FOR ORGANIC SYNTHESIS
REAGENTS FOR SILICON-MEDIATED ORGANIC SYNTHESIS

By:

Philip L. Fuchs (Editor)

Format:

Hardback

List price:

£107.00

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£96.30

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ISBN 10:

0470710233

ISBN 13:

9780470710234

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Publisher:

JOHN WILEY AND SONS LTD

Pub. date:

14 October, 2011

Series:

Handbook of Reagents for Organic Synthesis

Pages:

854

Description:

Synopsis:

Over the last three decades the importance of organosilicon chemistry has greatly increased because it has opened a number of new synthetic strategies. Silicon reagents are usually low-cost, versatile and allow a wide range of reactions. This is the first Handbook to compile essential Silicon containing reagents and makes use of the leading reagent database e-EROS. Another hot volume in the series Handbooks of Reagents for Organic Synthesis, this is a must-have resource for all synthetic chemists working in drug development and medicinal chemistry. For the selection the Editor focussed on three key synthetic approaches with the greatest impact: 1. Use of silicon as a 'temporary tether' by unifying a reactive pair of functional groups and taking advantage of their template-biased intramolecular cyclization. 2. The specific use of the silane functionality as a hetero t-butyl group, often colloquially referred to as the use of silicon as a 'fat proton'. 3. The use of the Brook rearrangement as an 'anion relay stratagem'.A new feature in this Handbook is the reagent finder, an alphabetically organized lookup table arranged by organic functionality and specific structure of the silicon atom to which it is bound.

Publication:

Imprint:

Wiley-Blackwell

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Returnable

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