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Item Details
| Title:
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THE BARBIER REACTION AND RELATED ONE-STEP PROCESSES
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| By: |
Cornelis Blomberg |
| Format: |
Hardback |
| List price:
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£84.99 |
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We currently do not stock this item, please contact the publisher directly for
further information.
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| ISBN 10: |
3540571698 |
| ISBN 13: |
9783540571698 |
| Publisher: |
SPRINGER-VERLAG BERLIN AND HEIDELBERG GMBH & CO. KG |
| Pub. date: |
16 December, 1993 |
| Series: |
Reactivity and Structure: Concepts in Organic Chemistry 31 |
| Pages: |
183 |
| Description: |
Offers a new perspective of the one-step organic synthesis method discovered by Barbier over 100 years ago. Tracing the development of synthetic applications of the Barbier reaction, the text also examines the detailed mechanism of the reaction and describes technical aspects. |
| Synopsis: |
The significant increase in applications of Barbier and Barbier-type reactions in (in-) organic synthesis over the past twenty-five years, combined with repeated stimulation on the part of Springer-Verlag (Dr. R. Stumpe) were strong in- centives for me to write this book. My earliest activities in this field include a modest and first-ever review article (in cooperation with Dr. F. A. Hartog who at that time (1977) did his doctoral research on the Barbier reaction). References to this review article, as mentioned in the Science Citation Index till recently are a good indication for a continued interest in this simple synthetic procedure. The subtitle of this monograph, Related One-Step Processes, may require the following clarification. A synthesis with the aid of an organometallic compound is usually carried out in two steps: 1) the organometallic reagent is prepared from an organo halide and a metal in a solvent, 2) a chosen substrate is added to this reagent. In a Barbier reaction these two steps are combined: a mixture of the organo halide and the substrate is added to a suspension of the metal-in an appropriate solvent. |
| Illustrations: |
49 Tables, black and white; XIII, 183 p. |
| Publication: |
Germany |
| Imprint: |
Springer-Verlag Berlin and Heidelberg GmbH & Co. K |
| Returns: |
Returnable |
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