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Item Details
Title: GMELIN: HANDBOOK OF INORGANIC AND ORGANOMETALLIC CHEMISTRY
Volume: 1
By: Kerstin Behrends
Format: Hardback

List price: £72.00


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ISBN 10: 3540936718
ISBN 13: 9783540936718
Publisher: SPRINGER-VERLAG BERLIN AND HEIDELBERG GMBH & CO. KG
Pub. date: 31 December, 1993
Edition: 8 ed
Pages: 248
Description: Two-thirds of this volume is devoted to triosmium carbonyl compounds, generally containing a triangular Os3 core, in which additional ligands are bonded to osmium3 by bridging carbon atoms. The final section deals with heterometallic carbonyl compounds containing additional ligands.
Synopsis: The present volume, "Organoosmium Compounds" 8 6, systematically covers the litera ture through 1992, including many later references. This volume is the first published of Series 8. This series is devoted to compounds containing two or more osmium atoms. The volume forms a unit with" Organoosmium Compounds" 8 5 (in preparation). 80th volumes deal with trinuclear compounds with ligands other than CO which are bonded to Os by one carbon atom ("1L ligands "), regardless of whether the ligand is additionally coordinated to Os by heteroatoms. Generally CO groups are additional ligands. As is usual in the organometallic Gmelin series, the term "trinuclear" means three osmium atoms in the molecule without regard to any additional metals that may be present. The content and the subdivision of both volumes are described on p. 1. Volume 85 will deal with homometallic compounds in which the bonding C atom of the leading 1L ligand is bonded to Os by one non-bridging Os-C bond. The first part of the present volume, 86, is devoted to homometallic compounds in which the bonding C atom of the 1L ligand bridges two or three Os atoms. A second part deals with all heterometallic compounds with 1L ligands other than CO. An Empirical Formula Index and a Ligand Formula Index for both volumes 8 5 and 86 will be included in volume 8 5. For abbreviations and dimensions used throughout this volume, see p. X."
Illustrations: 95 figures
Returns: Returnable
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